A new stereoselective synthesis of (Z)-vinylsilane allylic alcohols
โ Scribed by Kee D. Kim; Plato A. Magriotis
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 281 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Reaction of alkyllithiums 1 with isoprene epoxide 2 gives B,y-disubstituted allylic alcohols 2 of Z-configuration. The reaction of \*-lithiotricyclene as alkyllithium gives o-santalol 5, which is one of the main constituents in East Indian sandalwood oil.
## Abstract For Abstract see ChemInform Abstract in Full Text.
Although many conceptually different approaches for stereoselective preparation of allylie alcohols have been explored with considerable success, ' the importance of the allylic alcohol moiety in organic synthesis makes the ability to relocate it within a molecule an important and challenging proble