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A stereoselective 1,3-transposition reaction of allylic alcohols

✍ Scribed by Arata Yasuda; Hisashi Yamamoto; Hitosi Nozaki

Publisher: Elsevier Science
Year: 1976
Tongue: French
Weight: 139 KB
Volume: 17
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91750-7

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✦ Synopsis

Although many conceptually different approaches for stereoselective preparation of allylie alcohols have been explored with considerable success, ' the importance of the allylic alcohol moiety in organic synthesis makes the ability to relocate it within a molecule an important and challenging problem.

We have devised a new approach of some generality for the solution of this synthetic problem. The approach is schematized by the conversion& 4 II, involving the use of reductive elimination of epoxy

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