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ChemInform Abstract: Mild and Selective Boronic Acid Catalyzed 1,3-Transposition of Allylic Alcohols and Meyer—Schuster Rearrangement of Propargylic Alcohols.

✍ Scribed by Hongchao Zheng; Michal Lejkowski; Dennis G. Hall

Publisher
John Wiley and Sons
Year
2011
Weight
77 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

Highly electron‐deficient polyfluoroarylboronic acid catalysts (I)—(IV) are applied to the rearrangement of allylic alcohols and propargylic alcohols.

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ChemInform Abstract: 1,3-Transposition o
ChemInform Abstract: 1,3-Transposition of Allylic Alcohols Catalyzed by Methyltrioxorhenium.
✍ J. JACOB; J. H. ESPENSON; J. H. JENSEN; M. S. GORDON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

1,3-Transposition of Allylic Alcohols Catalyzed by Methyltrioxorhenium. -The kinetics and theoretical calculations of the 1,3-rearrangement of allylic alcohols with MeReO 3 catalyst to generate the more stable isomer are studied. The direction of the equilibrium is largely influenced by the nature o