1,3-Transposition of primary allylic alcohols: Synthesis of optically active secondary and tertiary allylic alcohols
✍ Scribed by Rosa L. Dorta; María S. Rodríguez; JoséA. Salazar; Ernesto Suárez
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 193 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Although many conceptually different approaches for stereoselective preparation of allylie alcohols have been explored with considerable success, ' the importance of the allylic alcohol moiety in organic synthesis makes the ability to relocate it within a molecule an important and challenging proble
1,3-Transposition of Allylic Alcohols Catalyzed by Methyltrioxorhenium. -The kinetics and theoretical calculations of the 1,3-rearrangement of allylic alcohols with MeReO 3 catalyst to generate the more stable isomer are studied. The direction of the equilibrium is largely influenced by the nature o
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