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A stereoselective total synthesis of (.+-.)-gymnomitrol

✍ Scribed by Welch, Steven C.; Chayabunjonglerd, Suthep


Book ID
121190033
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
285 KB
Volume
101
Category
Article
ISSN
0002-7863

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A new synthesis of (-)-rishitin (1) is reported, starting with chiral pool molecules. The crucial step is a stereo,selective vinyl radical eyelization, which gives a 10:1 ratio of 21 to 22.