Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co
Vibrationally excited NO2 from CH3NO2 and 2-C3H7NO2 photodissociation
โ Scribed by Kenneth G. Spears; Stephen P. Brugge
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 435 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The ultravlolct absorption spectra of H02NOz. CCl3O2NO2, CCl2r02N02, and CHJO~NO~ were measured from 210 10 280 nm The spectra arc snn~lar. and the absorption mtcnslty mcrcxcs as the w.wclcngth decreases wth a shoulder at =255 nm Axsummg that cvcry absorption lcnds to photodlssoclatlon. the photodwo
The single photon photodissociation of CH30N0, C2HsON0, and CsH,ONO has been studied under collision-free conditions using multiphoton ionization to detect the NO fragment. NO rotational -citation from CHsONO was very large (.&rot > 2100 cm-') and non-thermal, while QHsONO and C3H70NO produced NO wh
Pulse radiolysis was used to study the kinetics of the reactions of CH 3 C(O)CH 2 O 2 radicals with NO and NO 2 at By monitoring the rate of formation and decay of NO 2 295 K. using its absorption at the rate constants 400 and 450 nm k(CH C(O)CH O ฯฉ NO) ฯญ (8 ฯฎ 3 2 2 and were de-ฯช12 ฯช12 3 ฯช1 ฯช1 2) ฯซ
## Abstract Data in both directions for the title reaction have been statistically fit (weighted nonlinear least squares) to the different formalisms used by the NASA and IUPAC data evaluation panels. The data are well represented by either formalism. Master equation/RRKM methods were then employed