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Multiphoton ionization detection of photodissociation fragments: NO from CH3ONO, C2H5ONO, and C3H7ONO

✍ Scribed by G. Radhakrishnan; R.C. Estler

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
476 KB
Volume
100
Category
Article
ISSN
0009-2614

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✦ Synopsis

The single photon photodissociation of CH30N0, C2HsON0, and CsH,ONO has been studied under collision-free conditions using multiphoton ionization to detect the NO fragment. NO rotational -citation from CHsONO was very large (.&rot > 2100 cm-') and non-thermal, while QHsONO and C3H70NO produced NO which could be chrrncterized by Trot = 350 and 250 Ii respectively.

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## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.