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Fragmentation of Fe(CO)5ROH (R  CH3 and C2H5) heteroclusters induced by 248 nm multiphoton ionization

✍ Scribed by M.Y.M. Lyktey; P. Xia; J.F. Garvey

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 603 KB
Volume: 238
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00371-1

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✦ Synopsis

The ionic fragmentation of Fe(CO), within an environment of methanol or ethanol clusters was studied. Reflectron-timeof-flight mass spectrometry was employed to analyze the mixed cluster ions generated by 248 nm multiphoton ionization of [Fe(CO),][ROH],= 1_20 clusters (R = CH, or C,H,). The fragmentation patterns were found to be quite different from those observed in the gas and condensed phases. A mechanism for the fragmentation of alcohol cluster solvated metal carbonyls is proposed, which is consistent with previous studies in this area.

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