Vibrational relaxation of the A1 modes in methyl iodide
โ Scribed by N. Trisdale; M. Schwartz
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 298 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The Raman linewidths of the carbon-halogen stretching mode in several halobenzenes were measured as a function of temperature and in dilute cyclohexane solution\_ It was found that, as in an earlier investigation on haloalkanes, the vibrational relaxation efficiencies, pi;',, vary in the order Cl >
The temperature dependence of the linewidth of the Y] mode at 847 cm-' of the MnO: ion doped in KCIOI crystals has been investigated in the range 10-298 K by frequency-resolved resonant CARS. The results are discussed in terms of relaxation processes, through which the MnO; v, mode decays into combi
Picosecond relaxation times of C-H stretching vibrations in a series of liquid hydro&bons have been measured using the Kanxua sattering technique. The results indiate that the vibrational energy loss takes place primarily 'through the methyl groups in these molecules.
Vibrational energy relasation has been measured at Hz bath gas pressures from 1 lo 65000 Torr at 298 K in the competitive channel decomposition of 3-methyl-3-hexyl radicals chemically activated to ~44 kcal mol-I. Decomposition of the initially formed, internally non-randomized ndiuls occurs on a pic