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Vibrational excitation of CO in the reaction: O + CS → CO + S

✍ Scribed by G. Hancock; C. Morley; I.W.M. Smith

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
422 KB
Volume
12
Category
Article
ISSN
0009-2614

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✦ Synopsis

The relative raxes at which 0 + CS +CO + S populates individual vibrational levels of CO have been determined (a) from infrared chemiluminescence esperiments, and (b) by using a cw CO laser to measure CO vibrational distibutions produced when mixtures of CS2 + O2 are flash photolysed.

📜 SIMILAR VOLUMES

Infrared chemiluminescence from the reac
Infrared chemiluminescence from the reaction O + CS → CO + S
✍ G. Hancock; I.W.M. Smith 📂 Article 📅 1969 🏛 Elsevier Science 🌐 English ⚖ 386 KB

Vibrationally excited CO is produced in the reaction sequence: 0 + CS3 -SO + CS; 0 + CS -CO + S. and gives rise to infrared emission. At least 50% of the energy of the secondary reaction is converted to vibrational enerav. and it ia sussested that this mechanism causes stimulated emission in the CS2