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Infrared chemiluminescence from the reaction O + CS → CO + S

✍ Scribed by G. Hancock; I.W.M. Smith

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
386 KB
Volume
3
Category
Article
ISSN
0009-2614

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✦ Synopsis

Vibrationally excited CO is produced in the reaction sequence: 0 + CS3 -SO + CS; 0 + CS -CO + S. and gives rise to infrared emission. At least 50% of the energy of the secondary reaction is converted to vibrational enerav. and it ia sussested that this mechanism causes stimulated emission in the CS2 -02 flash photoiysis Taser.

The analysis of infrared chemiluminescence can reveal how a chemical reaction product is distributed amongst those vibrational quantum

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