✦ LIBER ✦

The infrared chemiluminescent reaction of Cl atoms with H2CO

✍ Scribed by D. M. Fasano; N. S. Nogar

Publisher: John Wiley and Sons
Year: 1981
Tongue: English
Weight: 377 KB
Volume: 13
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550130402

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✦ Synopsis

Abstract

The reaction Cl + H~2~CO → HCl + HCO has been studied at 295 K. Chlorine atoms were produced via the infrared laser induced dissociation of CCl~3~F, using a pulsed CO~2~ TEA laser. Using HCl infrared chemiluminescence as the diagnostic, we find the rate constant to be 7.4 ± 0.7 × 10^−11^ cm^3^/molecule sec, in good agreement with several recent studies. An evaluation of TEA laser photolysis as a technique for the generation of chlorine atoms is made, and the relationship of this experiment to recent theories of infrared laser induced chemistry is discussed.

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