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Vibrational excitation of CO from the reaction C + O2

โœ Scribed by E.A. Ogryzlo; J.P. Reilly; B.A. Thrush

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
209 KB
Volume
23
Category
Article
ISSN
0009-2614

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The relative raxes at which 0 + CS +CO + S populates individual vibrational levels of CO have been determined (a) from infrared chemiluminescence esperiments, and (b) by using a cw CO laser to measure CO vibrational distibutions produced when mixtures of CS2 + O2 are flash photolysed.

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The infrared emission observed from Hz0 or Co, when added to discharged oxygen containing Oz(r Zg> and C&(lA ) is shown to arise from their vibrational excitation in the quenching of Oz(\* $'). There was no ev&nce that O$'X> is quenched to the ground state rather than to the ' 4 state.