The CS + (A2Hi-X 2~+ ) emission has been observed in the C + (2p)+ocs reaction at thermal energy in a flowing afterglow apparatus. New bands of CS + (A 2 II~-X 2~ + ) from v'= 10-14 to v"= 0-3 were identified. The vibratio.nal populations in the CS + (A21-I~) state were estimated by spectral simulat
Chemiluminescent reaction at thermal energy: Vibrational distribution of CO+(A 2Π) from the C+ O2 reaction
✍ Scribed by Masaharu Tsuji; Toshihiko Susuki; Minoru Endoh; Yukio Nishimura
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 280 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
CO*(A "ll-X 2P) emission produced from the C(2P) + O2 reaclm hss been observed al thermal cncrgy III a flowing afterdow apparatus. The relabve vIbrational population In the CO*(A %I) state was dctcrrnmcd The avcngc fmctlon of VIbntional cncrgy dwrbulcd m CO+(A Zn).(/vJ. ws estimated to be 0.20 i 0 02
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The extensive bands observed from the hehum afterglow reaction of SO\* m the 250-540 mn region are assigned to the new SO+(A \*rt--X\*l$) system produced from the He\*/S02 dissociative charge-transfer reaction at themA energy. They had been erroneously mterpreted as the SO; (c-4 system produced from
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OCS+ (x-z) emission has heen observed from the thermal energy charge transfer reaction between N; ions and OCS molecules. The rotational temperatures of the OCS+ (A 21T,: O") state were estimated to be 23OOk 300 K for D = 3/2 and 3300 + 500 K for O= 112, by assuming a single Boltzmann distribution.