CO\*(A "ll-X 2P) emission produced from the C(2P) + O2 reaclm hss been observed al thermal cncrgy III a flowing afterdow apparatus. The relabve vIbrational population In the CO\*(A %I) state was dctcrrnmcd The avcngc fmctlon of VIbntional cncrgy dwrbulcd m CO+(A Zn).(/vJ. ws estimated to be 0.20 i 0
Chemiluminescent reaction at thermal energy: The CS+ (A2Π, −X2∑+) emission produced from the C+(2P) + OCS reaction
✍ Scribed by Kazumi Mizukami; Hiroshi Obase; Masaharu Tsuji; Yukio Nishimura
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 306 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
The CS + (A2Hi-X 2~+ ) emission has been observed in the C + (2p)+ocs reaction at thermal energy in a flowing afterglow apparatus. New bands of CS + (A 2 II~-X 2~ + ) from v'= 10-14 to v"= 0-3 were identified. The vibratio.nal populations in the CS + (A21-I~) state were estimated by spectral simulation.
📜 SIMILAR VOLUMES
The extensive bands observed from the hehum afterglow reaction of SO\* m the 250-540 mn region are assigned to the new SO+(A \*rt--X\*l$) system produced from the He\*/S02 dissociative charge-transfer reaction at themA energy. They had been erroneously mterpreted as the SO; (c-4 system produced from
The OCS'(A 'lTrrR 'Up: Q= l/2,3/2) emission resultmg from the Ar+('P,,,) +OCS charge-transfer reaction has been reexamined in a low-pressure flowing afterglow. The fluorescence channel in the the 0" level was found to be open for rotationally excited levels up to Jz 170 ( z 5500 cm-'). The rotation
## CS? in an Ar afterglow eshibircd rrnission from the 0'. 1' and 2' levels of CSG(x 'n,-% 'II,). The excitation source was attributed to Ar;. The vibrational frequencies of CS;(.?: U: = 4 and u'; + $u: = 3) were detcrkined from the vibrational analysis of the (u'; ,&.O) progressions from the O" l
\(\mathrm{N}_{2}^{+}\left(\mathrm{B}^{2} \Sigma_{\mathrm{u}}^{+}-\mathrm{X}^{2} \Sigma_{\mathrm{g}}^{+}\right)\)emission was observed from the near-resonant charge transfer between \(\mathrm{Ne}_{2}^{+}\)and \(\mathrm{N}_{2}\). Vibrational populations for \(v^{\prime}=0\) and 1 of \(N_{2}^{+}(B)\) w