In order to examine the solvating strength toward a cation species N: , the equilibria of clustering reactions N: (Ar).\_, + 2Ar=N: (Ar),+Ar were studied with a pulsed electron beam high-pressure mass spectrometer. the thermochemical stabilities of N$ ( Ar ), with n > 2 were determined. The bond ene
CS2+(A-X) emission produced from the charge-transfer reaction of Ar2+ with CS2 in the Ar afterglow
โ Scribed by Minoru Endoh; Masaharu Tsuji; Yukio Nishimura
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 476 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
CS? in an
Ar afterglow eshibircd rrnission from the 0'. 1' and 2' levels of CSG(x 'n,-% 'II,). The excitation source was attributed to Ar;. The vibrational frequencies of CS;(.?: U: = 4 and u'; + $u: = 3) were detcrkined from the vibrational analysis of the (u'; ,&.O) progressions from the O" level. The relative vibrational population shows a significant deviation from a Fran&-Condon distribution_
๐ SIMILAR VOLUMES
The CS + (A2Hi-X 2~+ ) emission has been observed in the C + (2p)+ocs reaction at thermal energy in a flowing afterglow apparatus. New bands of CS + (A 2 II~-X 2~ + ) from v'= 10-14 to v"= 0-3 were identified. The vibratio.nal populations in the CS + (A21-I~) state were estimated by spectral simulat
The CS( A 'nL+X 'Z+) emission spectra resulting from the energy transfer reaction of Ar(3P,) +CSz under single collision condition have been obtained. The relative vibrational populations of the nascent product CS(A 'lT, u') have been determined by means of spectral simulation. A population inversio
\(\mathrm{N}_{2}^{+}\left(\mathrm{B}^{2} \Sigma_{\mathrm{u}}^{+}-\mathrm{X}^{2} \Sigma_{\mathrm{g}}^{+}\right)\)emission was observed from the near-resonant charge transfer between \(\mathrm{Ne}_{2}^{+}\)and \(\mathrm{N}_{2}\). Vibrational populations for \(v^{\prime}=0\) and 1 of \(N_{2}^{+}(B)\) w