The reaction of CH2, particularly the ground electronic state triplet CH2 [l], with 0 2 is known to be very fast. The effectiveness of the reactions involving both singlet (lCH2) and triplet (3CH2) methylene was most dramatically demonstrated by the drastic effects of O2 on CO laser emissions in bot
Excitation of the Asymmetric Stretch Vibration of CO2 in OH+CO→H+CO2 Reaction
✍ Scribed by Congyun Shi; Li Ren; Fanao Kong
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 108 KB
- Volume
- 7
- Category
- Article
- ISSN
- 1439-4235
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The rate coefficients for the reactions were determined using mixtures of HN03/CO/Ar and HN03/HNCO/Ar in incident shock wave experiments Simultaneous OH and COz absorption time-histories were obtained via cw uv narrow-linewidth absorption at 32606 56 cm-' ( A = 306 687 nm) and cw infrared narrowlin
Spectra of CH 4 / O 2 low-pressure flames have been recorded at a resolution of 0.020 cm 01 with an infrared Fourier transform spectrometer in the spectral range 1790 to 5029 cm 01 . Through the use of CO 2 and CO emission lines, the flame temperature has been determined with a precision of the orde
Calculations using the coupled-cluster method with singles and doubles Ž . based on a restricted open Hartree-Fock reference ROHF-CCSD with the augЈ-cc-pVDZ basis set have been carried out to investigate the structures, energies, and vibrational spectra of protonated H CO and of the hydrogen-bonded