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Vibrational deactivation of CO2(0001) by ethane

✍ Scribed by I.Veerabhadra Rao; Y.V.Chalapati Rao; S.V. Babu; V.Subba Rao

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 403 KB
Volume: 28
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80088-6

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✦ Synopsis

The deactivation of C&(OO"l) by ethane in.ihe temperature ran9 300-600 K has been strrdied using 2 laser induced fluorescence technique. Thhd energ transfer cross section dccrased from 0.23 A2 at 3CO K to 0.16 AZ at 600 K. The magnitude of the cross section is consistent with the expectation that ncx tCSOMIlt V-V energy transfcr processes are responsible for the energ tnqsfer between COz(OO" L) and cthane during coUisions even thOu$ the observed temperature dependence of the enera transfer cross section does not follow that predicted by the CXisting theories.

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