The deactivation of C&(OO"l) by ethane in.ihe temperature ran9 300-600 K has been strrdied using 2 laser induced fluorescence technique. Thhd energ transfer cross section dccrased from 0.23 A2 at 3CO K to 0.16 AZ at 600 K. The magnitude of the cross section is consistent with the expectation that nc
Collisional deactivation of CO2(0001) by propyl alcohols
โ Scribed by V. Sasi Dhar; Y.V. Chalapati Rao
- Publisher
- Elsevier Science
- Year
- 1977
- Tongue
- English
- Weight
- 253 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The collisional &activation ot COz(OOO 1) by n-prtrpyl am1 rso-propyl :11c01101 hnr been wdied using the lw~ evctted fhoresccncc method in the tcmpCratUrc range 303-514 K. The cncrgy transfer cros wctl0n5 dccrcascd wltlr increa4inp temperature and near-reson&lnt V-V energy trnnsfcr procclsses 9r(: ttwugiit to be rcspondbie for tile denctivati0~ of CO2 too0 1).
๐ SIMILAR VOLUMES
Collisional deactivation rate constants of CO+ A 'fI(v=O and 2) by He, Ne. Ar, N,, and CO have been determined by using a time-resolved laser-induced fluorescence technique. The results were combined with the previously determined Y= 1 rate constants to obtain an interesting u dependence of the rate
The rate constrtnt k& of the dcxtiration of the states (02'0. lO\*O)t. (O;Z'O. 10'O)t1 and (OZ20), assumed in mutual equilibrium, 10wmis (01'0) is mrxwmxf betaecn 170 nnd 300 Kc; the rate constant KbS nbich characterizes the deactivation of aLI r)mmetric-strctching and bertdins ItwIs is measured fro
A photoacoustic method is used under such experimental conditions that the (01'0) level ofC02 gas is not in e@li%rinrn with the other vibrational Ievck The rate mnsta.ntsk;o characterizing the CO2 (01'0) collisional deactivation by Nz, CO aad 02 are measured directly.
Rate constants for deactivation of PII& 'X". u = 0) bv N=. CO. NO. H+.and He bare been determined b) time resohed \_ quenching measurements of the emission bands\_ Values (in =,3 moIecuIe-l