Determination of energy transferred to rotation-translation in deactivation of CO2(0001) by N2 and O2 and of CO(1) by CO2
โ Scribed by J. Taine; F. Lepoutre
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 369 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
A photoacoustic method is used under such experimental conditions that the (01'0) level ofC02 gas is not in e@li%rinrn with the other vibrational Ievck The rate mnsta.ntsk;o characterizing the CO2 (01'0) collisional deactivation by Nz, CO aad 02 are measured directly.
Collisional deactivation rate constants of CO+ A 'fI(v=O and 2) by He, Ne. Ar, N,, and CO have been determined by using a time-resolved laser-induced fluorescence technique. The results were combined with the previously determined Y= 1 rate constants to obtain an interesting u dependence of the rate
have been performed with the laser excited fluorescence method of the rates of vibratianal drcrctivation of the upper CO2 laser level by ONF, COF;? and 03. In each cast, rapid near-resonant V + V transfer deactivation mechanisms are indicated.
The quenching of electronically excited chlorine atoms, CI( 3 'PI ?). by several gases has been studied using a small gain laser pulse method, based on photochemical Cl and I lasers, operating on spin-orbit transitions 2P,,Z,F+\*P3,Z,F... The quenching efliciencies for HZ, D,, CO, and SF6 are shown
The rate constrtnt k& of the dcxtiration of the states (02'0. lO\*O)t. (O;Z'O. 10'O)t1 and (OZ20), assumed in mutual equilibrium, 10wmis (01'0) is mrxwmxf betaecn 170 nnd 300 Kc; the rate constant KbS nbich characterizes the deactivation of aLI r)mmetric-strctching and bertdins ItwIs is measured fro