✍ Scribed by Terrill A. Cool; J.Richard Airey
No coin nor oath required. For personal study only.
have been performed with the laser excited fluorescence method of the rates of vibratianal drcrctivation of the upper CO2 laser level by ONF, COF;? and 03. In each cast, rapid near-resonant V + V transfer deactivation mechanisms are indicated.
📜 SIMILAR VOLUMES
The infrared emission observed from Hz0 or Co, when added to discharged oxygen containing Oz(r Zg> and C&(lA ) is shown to arise from their vibrational excitation in the quenching of Oz(\* $'). There was no ev&nce that O$'X> is quenched to the ground state rather than to the ' 4 state.
Vibration to vibration and rotation (WR) exchange occurs between CO and D, over the temperature range 340 K to 230 K, whilst at lower temperatures VT deactivation is dominant. Probabilities for these processes and for D, -D, deactivation are presented.
NO, was photolyzed with 2288 A radiation at 300" and 423'K in the presence of H 2 0 , The photolysis produces O(lD) atoms which react with CO, and in some cases excess He. H20 to give H O radicals (3) O(lD) + H20 -+ 2 H 0 or are deactivated by CO to O ( 3 P ) atoms (5) O ~D ) The ratio kJkS is temp