✦ LIBER ✦

Temperature dependence of intramolecular vibrational energy transfer in CO2: CO2(0001) + Ne/CO2 → CO2(nml0) + Ne/CO2

✍ Scribed by Hyung Kyu Shin

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 539 KB
Volume: 40
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)85087-7

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✦ Synopsis

intramoleculv vibration--vibration energy transfer cross sections ha--e been calculated for COs(OO" 1) -I-Ne and COa(OO" 1) + COa (OOOO) over the tempemture range 100-3000 K. It is shown that (00'1) + (11'0) is the most important process at lower temperatures, while (00'1) + (10'0) dominates others et higher temperatures. The temper&tire dependence of (00'1) -+ (10'0) $ very strong compared with that of (00'1) 4 (11'0). Calculations show that the sum of the total cross sections of these two processes and that of (00'1) + (20'0) is close to experimental data.

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