UV-laser-induced photolysis of trimethyl(vinyloxy)silane for chemical vapour deposition of polysiloxane films
✍ Scribed by Akihiko Ouchi; Yoshinori Koga; Zdeněk Bastl; Josef Pola
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 280 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0268-2605
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✦ Synopsis
The UV-induced photolysis of trimethyl(vinyloxy)silane (TMVSi) induced by ArF laser, affording a multitude of unsaturated hydrocarbons and a solid polydimethylsiloxane, represents a convenient process of chemical vapour deposition in which the silicon of the parent is almost completely utilized for the formation of the solid phase and in which the morphology and composition of the films is affected by the configuration of the substrate and laser beam.
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## Continuous -wave CO 2 -laser-induced gas-phase decomposition of H 3 SiOSiH 3 , dominated by elimination and polymerization of transient silanone H 2 Si=O and yielding silane and hydrogen as side-products, represents a convenient process for chemical vapour deposition of poly(hydridosiloxane) fi