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Unusual C→N migration of phosphoryl group; synthesis of N′-phosphorylated amidines

✍ Scribed by Jang, Won Bum; Oh, Dong Young


Book ID
119938009
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
46 KB
Volume
5
Category
Article
ISSN
1359-7345

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📜 SIMILAR VOLUMES


N → C2 → C3 migration of the dichloropho
✍ Aleksandra A. Chaikovskaya; Yurii V. Dmytriv; Nadiya V. Shevchuk; Radomyr V. Sma 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 101 KB

## Abstract A successive N → C~2~ → C~3~ migration of the dichlorophosphino group has been found to occur in phosphorylation of unsubstituted pyrrole with phosphorus trichloride. As a result of this migration, a number of hitherto unknown C‐phosphorylated N‐unsubstituted pyrroles have been obtained

N → C3 migration of dichlorophosphino gr
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## Abstract A N → C~3~ migration of the dichlorophosphino group has been revealed in the phosphorylation of unsubstituted indole with phosphorus trichloride. Several 3‐phosphorylated NH‐indole derivatives have thus been obtained and N‐acylation of one of the products has been performed. © 2009 Wile

C-phosphorylation of n-methylpyrrole
✍ Sergey P. Ivonin; Tetjana E. Terikovska; Alexandra A. Chaikovskaya; Anatoliy P. 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB

The phosphorylation of N-methylpyrrole with phosphorus (III) halides has been studied. Migration of the dibromophosphino group from the second to the third position of N-methylpyrrole, leading to the 3-dibromophosphine, has been found. Methods for the synthesis of 2,4-bisphosphorylated pyrroles have