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N → C3 migration of dichlorophosphino group in the phosphorylation of N-unsubstituted indole with phosphorus trichloride

✍ Scribed by Aleksandra A. Chaikovskaya; Yurii V. Dmytriv; Nadiya V. Shevchuk; Radomyr V. Smaliy; Aleksander M. Pinchuk; Andrey A. Tolmachev

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
80 KB
Volume
20
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

A N → C~3~ migration of the dichlorophosphino group has been revealed in the phosphorylation of unsubstituted indole with phosphorus trichloride. Several 3‐phosphorylated NH‐indole derivatives have thus been obtained and N‐acylation of one of the products has been performed. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:235–239, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20540

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## Abstract A successive N → C~2~ → C~3~ migration of the dichlorophosphino group has been found to occur in phosphorylation of unsubstituted pyrrole with phosphorus trichloride. As a result of this migration, a number of hitherto unknown C‐phosphorylated N‐unsubstituted pyrroles have been obtained