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N → C2 → C3 migration of the dichlorophosphino group in the synthesis of phosphorylated NH-pyrroles

✍ Scribed by Aleksandra A. Chaikovskaya; Yurii V. Dmytriv; Nadiya V. Shevchuk; Radomyr V. Smaliy; Aleksander M. Pinchuk; Andrey A. Tolmachev

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
101 KB
Volume
19
Category
Article
ISSN
1042-7163

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✦ Synopsis

Abstract

A successive N → C~2~ → C~3~ migration of the dichlorophosphino group has been found to occur in phosphorylation of unsubstituted pyrrole with phosphorus trichloride. As a result of this migration, a number of hitherto unknown C‐phosphorylated N‐unsubstituted pyrroles have been obtained. © 2008 Wiley Periodicals, Inc. Heteroatom Chem 19:671–676, 2008; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20495

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