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ChemInform Abstract: Reversible C⇔N Migration of the Ethoxycarbonyl Group in Pyridinium Ylides.

✍ Scribed by Yu. G. Gololobov; O. V. Dovgan'; I. Yu. Krasnova; P. V. Petrovskii; I. A. Garbuzova


Publisher
John Wiley and Sons
Year
2001
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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Abstract

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Reversible C ⇆ N migration of the ethoxy
✍ Yuri G. Gololobov; Olga V. Dovgan; Igor R. Golding; Pavel V. Petrovskii; Irina A 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 221 KB 👁 2 views

## Abstract Pyridinium and isoquinolinium ylides (**__7__** and **__12__**) derived from malonic ester react in an unusual manner with isocyanates giving the new pyridinium ylide (**__9__**) and the new isoquinolinium ylide (**__14__**). __C__ → __N__ Migration of the COOEt group takes place at roo