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C-phosphorylation of n-methylpyrrole

✍ Scribed by Sergey P. Ivonin; Tetjana E. Terikovska; Alexandra A. Chaikovskaya; Anatoliy P. Marchenko; Georgiy N. Koydan; Alexander M. Pinchuk; Andrew A. Tolmachev

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 190 KB
Volume: 10
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(1999)10:3<213::aid-hc7>3.0.co;2-g

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✦ Synopsis

The phosphorylation of N-methylpyrrole with phosphorus (III) halides has been studied. Migration of the dibromophosphino group from the second to the third position of N-methylpyrrole, leading to the 3-dibromophosphine, has been found. Methods for the synthesis of 2,4-bisphosphorylated pyrroles have been developed.

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