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Unraveling the Bite Angle Effect: New Ligands for Selective Hydroformylation of Internal Alkenes

โœ Scribed by Lars A. van der Veen; Paul C. J. Kamer; Piet W. N. M. van Leeuwen

Publisher
John Wiley and Sons
Year
2003
Weight
52 KB
Volume
34
Category
Article
ISSN
0931-7597

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The Effect of the Bite Angle of Diphosph
The Effect of the Bite Angle of Diphosphane Ligands on Activity and Selectivity in Palladium-Catalyzed Allylic Alkylation
โœ Mirko Kranenburg; Paul C. J. Kamer; Piet W. N. M. van Leeuwen ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 295 KB ๐Ÿ‘ 2 views

The effect of the natural bite angle (ฮฒ n ) of diphosphane li-angle of the ligand becomes larger. This results in an increasing selectivity at larger bite angles, but at very large gands on catalyst selectivity and activity in the palladiumcatalyzed allylic alkylation was investigated. The selectivi