New Phosphorus Ligands for the Rhodium-Catalyzed Isomerization/Hydroformylation of Internal Octenes
✍ Scribed by Detlef Selent; Dieter Hess; Klaus-Diether Wiese; Dirk Röttger; Christine Kunze; Armin Börner
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 71 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0044-8249
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## Abstract The synthesis of calix[4]arene‐based phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)‐ catalyzed hydroformylation of 1‐octene. Depending on the reaction conditions, yields up to 99% and __n/iso__‐selectivities between 0.7 and 2.6 h
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