ChemInform Abstract: Tetraphenol-Based Diphosphite Ligands: Synthesis, Characterization, and Application in the Rhodium-Catalyzed Hydroformylation of Octenes.
β Scribed by Michele Janssen; Laura Bini; Bart Hamers; Christian Mueller; Dieter Hess; Andrea Christiansen; Robert Franke; Dieter Vogt
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 26 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The synthesis of calix[4]areneβbased phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)β catalyzed hydroformylation of 1βoctene. Depending on the reaction conditions, yields up to 99% and __n/iso__βselectivities between 0.7 and 2.6 h
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