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The Effect of the Bite Angle of Diphosphane Ligands on Activity and Selectivity in Palladium-Catalyzed Cross-Coupling

✍ Scribed by Mirko Kranenburg; Paul C. J. Kamer; Piet W. N. M. van Leeuwen


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
326 KB
Volume
1998
Category
Article
ISSN
1434-1948

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The effect of the natural bite angle (Ξ² n ) of diphosphane li-angle of the ligand becomes larger. This results in an increasing selectivity at larger bite angles, but at very large gands on catalyst selectivity and activity in the palladiumcatalyzed allylic alkylation was investigated. The selectivi

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