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Unprecedented nucleophilic addition of organolithiums to aromatic aldehydes and ketones by complexation with aluminum tris(2,6-diphenylphenoxide).

โœ Scribed by Maruoka, Keiji; Ito, Masahiro; Yamamoto, Hisashi


Book ID
125488363
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
209 KB
Volume
117
Category
Article
ISSN
0002-7863

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โœ S. SAITO; K. SHIMADA; H. YAMAMOTO; E. MARTINEZ DE MARIGORTA; I. FLEMING ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 2 views

Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products