Diastereoselective Addition of Organolithiums to 1,3-Oxazolidines Complexed with Aluminum Tris(2,6-diphenylphenoxide) (ATPH).
β Scribed by Takayasu Yamauchi; Hiroyuki Sazanami; Yuuichi Sasaki; Kimio Higashiyama
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 22 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products
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