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ChemInform Abstract: Unprecedented Nucleophilic Addition of Organolithiums to Aromatic Aldehydes and Ketones by Complexation with Aluminum Tris(2,6- diphenylphenoxide).

✍ Scribed by K. MARUOKA; M. ITO; H. YAMAMOTO

Book ID: 112024334
Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 26
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199552052

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Unprecedented nucleophilic addition of o

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ChemInform Abstract: Efficient Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds by Complexation with Aluminum Tris(2,6-diphenylphenoxide).

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ChemInform Abstract: A New Synthetic Rou

ChemInform Abstract: A New Synthetic Route to Allylsilanes: The Reaction of Silyllithium Reagents with Aromatic Carbonyl Compounds and Aluminum Tris(2,6- diphenylphenoxide) (ATPH).

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Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products

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