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Diastereoselective addition of organolithiums to 1,3-oxazolidines complexed with aluminum tris(2,6-diphenylphenoxide) (ATPH)

โœ Scribed by Takayasu Yamauchi; Hiroyuki Sazanami; Yuuichi Sasaki; Kimio Higashiyama


Book ID
108282858
Publisher
Elsevier Science
Year
2005
Tongue
French
Weight
244 KB
Volume
61
Category
Article
ISSN
0040-4020

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Tris(2,6-diphenylphenoxide) (ATPH). -1,6-Addition of silyllithium reagents to aromatic carbonyl compound ATPH complex and following enolate capture with an appropriate electrophilic reagent leads to functionalized allylsilanes shown in the scheme. In the reaction of (I), aromatic silylated products