## Abstract The thermal decomposition of ammonia was studied by means of the shockβtube and vacuum ultraviolet absorption spectroscopy monitoring the concentration of atomic hydrogen. The rate constants of both the initiation reaction equation image and the consecutive reaction equation image w
Unimolecular decomposition of the phenoxy radical in shock waves
β Scribed by Chin-Yu Lin; M. C. Lin
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 176 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0538-8066
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The shock-initiated decomposition of tetramethylgermane (107%1242 K ) has been found to involve successive elimination of methyl radicals with the rate constant k l for the first step given by log k l (s-') = (17.00 f 0.35) -(77.0 f 1.9)/0 kcal/mol In the presence of excess toluene the products were
## Abstract The kinetic energy relased on the loss of a CH~3~ β radical from __para__ substituted anisoles appears to depend on the nature of the substituent. The application of the dual parameter equation of Yukawa and Tsuno yields a linear correlation with the __T__~0.5~βvalues. The mesomeric eff