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Effect of substituents on the kinetic energy release in unimolecular decompositions of substituted anisoles

✍ Scribed by Helena Florêncio; Peter C. Vijfhuizen; Wigger Heerma; Geo Dijkstra

Publisher
John Wiley and Sons
Year
1979
Tongue
English
Weight
288 KB
Volume
14
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The kinetic energy relased on the loss of a CH~3~ ⋅ radical from para substituted anisoles appears to depend on the nature of the substituent. The application of the dual parameter equation of Yukawa and Tsuno yields a linear correlation with the T~0.5~‐values. The mesomeric effect predominates strongly over the inductive effect.

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