The unimolecular decomposition of methyl nitrite in the temperature range 680-955 K and pressure range 0.64 to 2.0 atm has been studied in shock-tube experiments employing real-time absorption of CW CO laser radiation by the NO product. Computer kinetic modeling using a set of 23 reactions shows tha
Thermal decomposition of ammonia in shock waves
β Scribed by M. Yumura; T. Asaba; Y. Matsumoto; H. Matsui
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 500 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0538-8066
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β¦ Synopsis
Abstract
The thermal decomposition of ammonia was studied by means of the shockβtube and vacuum ultraviolet absorption spectroscopy monitoring the concentration of atomic hydrogen. The rate constants of both the initiation reaction
equation image
and the consecutive reaction
equation image
were determined directly as
and
respectively.
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