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Shock-initiated decomposition of tetramethylgermane and the reaction of methyl radicals with toluene

✍ Scribed by J. Dzarnoski; M. A. Ring; H. E. O'Neal

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 428 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140308

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✦ Synopsis

The shock-initiated decomposition of tetramethylgermane (107%1242 K ) has been found to involve successive elimination of methyl radicals with the rate constant k l for the first step given by log k l (s-') = (17.00 f 0.35) -(77.0 f 1.9)/0 kcal/mol In the presence of excess toluene the products were CH4 (major), C2H4, and C2He. Results relevant to the reaction of methyl radicals with toluene compared to methyl radical recombination are discussed.

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