The title complex, (C 6 H 18 N 2 )[V 2 Cl 5 (C 6 H 16 N 2 ) 2 ](C 24 H 20 B).-C 4 H 8 O, was prepared by the reaction of [V 2 Cl 3 (THF) 6 ](BPh 4 ) with [FeCl 2 (tmeda) 2 ] in the presence of one equivalent of tmeda (tmeda = N,N,N H ,N H -tetramethylethylenediamine) in methanol. The crystal structu
✦ LIBER ✦
Tris(N,N,N′,N′-tetramethylguanidinium) nonabromodiantimonate(III)
✍ Scribed by Bujak, Maciej ;Zaleski, Jacek
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 424 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title compound, [NH 2 C(N(CH 3 ) 2 ) 2 ] 3 [Sb 2 Br 9 ], the organic cations interact with the isolated [Sb 2 Br 9 ] 3À anions by way of N-HÁ Á ÁBr hydrogen bonds, leading to some deformations of the inorganic unit.
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