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Tris(1,10-phenanthroline)iron(II) diperchlorate hemihydrate

✍ Scribed by Koh, L. L. ;Xu, Y. ;Hsieh, A. K. ;Song, B. ;Wu, F. ;Ji, L.


Book ID
114510775
Publisher
International Union of Crystallography
Year
1994
Tongue
English
Weight
335 KB
Volume
50
Category
Article
ISSN
0108-2701

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The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,1

Tris(1,10-phenanthroline)cobalt(II) trii
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The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol