Tris(1,10-phenanthroline)iron(II) diperchlorate hemihydrate
✍ Scribed by Koh, L. L. ;Xu, Y. ;Hsieh, A. K. ;Song, B. ;Wu, F. ;Ji, L.
- Book ID
- 114510775
- Publisher
- International Union of Crystallography
- Year
- 1994
- Tongue
- English
- Weight
- 335 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0108-2701
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📜 SIMILAR VOLUMES
The title compound, [Ni(C 8 H 6 N 2 ) 3 ][Mo 6 O 19 ], contains centrosymmetric [Mo 6 O 19 ] 2À hexamolybdate anions, which are built up from distorted MoO 6 units by edge-sharing. The nickel atom in the [Ni(phen) 3 ] 2+ cation adopts distorted octahedral coordination with three N,N 0 -bidentate 1,1
The asymmetric unit of the title compound, [Co(C 12 H 8 N 2 ) 3 ]-(I 3 ) 2 , contains one [Co(1,10-phenanthroline) 3 ] 2+ cation, half each of two centrosymmetric triiodide anions, and one complete triiodide anion. The title compound was synthesized solvothermally from Co(NO 3 ) 2 , 1,10-phenanthrol