Tris(1,10-phenanthroline-5,6-dione-κ 2N , N ′)zinc bis(perchlorate) acetonitrile monosolvate
✍ Scribed by Zhao, Jing; Zhang, Heng; Zhang, Zhaozhi; Zhao, Haiyan; Zhu, Guoyi
- Book ID
- 121530249
- Publisher
- International Union of Crystallography
- Year
- 2011
- Tongue
- English
- Weight
- 681 KB
- Volume
- 67
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Cu(C~12~H~6~N~2~O~2~)~3~](ClO~4~)~2~·4.5H~2~O, the Cu^II^ atom is in a distorted octahedral environment with unequal Cu—N distances, due to the Jahn–Teller elongation of the two Cu—N bonds in __trans__ positions. The crystal studied was an inversion twin..
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê R factor = 0.085 wR factor = 0.168 Data-to-parameter ratio = 12.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
catena-Poly[[[bis(acetonitrile) (1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)]-l-perchloratoj 2 O:O 0 0 0 ] perchlorate]
Single-crystal X-ray study T = 180 K Mean (C-C) = 0.007 A Some non-H atoms missing R factor = 0.045 wR factor = 0.131 Data-to-parameter ratio = 20.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.