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Trinuclear Mo(IV) cluster ion with a propylidyne cap

โœ Scribed by Avi Bino; Dan Gibson


Book ID
104138919
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
132 KB
Volume
65
Category
Article
ISSN
0020-1693

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Procedures for the conversion of ฮผ2Sโ†’ฮผ2O
โœ Liu Qiu-Tian; Jiaxi Lu; A. Geoffrey Sykes ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 376 KB

The reaction of trinuclear MO(N), incomplete cuboidal complexes [Mo,S,(H,O),]~+, [Mo,OS,(H,O),]~+ and Fro,W,W,W4+ with BH.,-in aqueous HCl solutions results in the conversion of core ligands A-S to h-0. In combination with Dowex cation-exchange chromatography the procedure can be used on a preparati