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A quasi-layer structure of trinuclear molybdenum(IV) cluster, [Mo3S7(S2CNEt2)3]I·S8

✍ Scribed by Can-Zhong Lu; Jun-Ning Zhuang; Li-Sheng Chi; Yin-Gui Wang; Jin-Shun Huang; Hong-Hui Zhuang; Qian-Er Zhang

Book ID
110275538
Publisher
Springer
Year
1999
Tongue
English
Weight
80 KB
Volume
29
Category
Article
ISSN
1572-8854

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Procedures for the conversion of μ2S→μ2O
Procedures for the conversion of μ2S→μ2O in trinuclear Mo(IV)3 incomplete cuboidal Mo/S cluster complexes
✍ Liu Qiu-Tian; Jiaxi Lu; A. Geoffrey Sykes 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 376 KB

The reaction of trinuclear MO(N), incomplete cuboidal complexes [Mo,S,(H,O),]~+, [Mo,OS,(H,O),]~+ and Fro,W,W,W4+ with BH.,-in aqueous HCl solutions results in the conversion of core ligands A-S to h-0. In combination with Dowex cation-exchange chromatography the procedure can be used on a preparati