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A Mixed-Valence Polyoxovanadate(III,IV) Cluster with a Calixarene Cap Exhibiting Ferromagnetic V(III)−V(IV) Interactions

✍ Scribed by Aronica, Christophe; Chastanet, Guillaume; Zueva, Ekaterina; Borshch, Serguei A.; Clemente-Juan, Juan M.; Luneau, Dominique

Book ID
111864933
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
168 KB
Volume
130
Category
Article
ISSN
0002-7863

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The Monophosphate Pb2V2VO(PO4)4: A Tunne
The Monophosphate Pb2V2VO(PO4)4: A Tunnel Structure with the Mixed Valence V(III)-V(IV)
✍ A. Leclaire; J. Chardon; A. Grandin; M.M. Borel; B. Raveau 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 420 KB

A new vanadium monophosphate, \(\mathrm{Pb}_{2} \mathrm{~V}_{2} \mathrm{VO}\left(\mathrm{PO}_{4}\right)_{4}\), characterized by the mixed valence V(III)-V(IV), has been synthesized. It crystallizes in the space group \(C 2 / c\) with \(a=17.747(2) \AA, b=\) 18.051(2) \(\AA, c=9.344(1) \AA\), and \(\