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Electrochemical studies of vanadium(III), -(IV), and -(V) complexes of 8-quinolinol in acetonitrile. Formation of a binuclear mixed-valence (IV,V) complex

✍ Scribed by Riechel, Thomas L.; Sawyer, Donald T.

Book ID
126129654
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
917 KB
Volume
14
Category
Article
ISSN
0020-1669

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Identification of the oxidation product
Identification of the oxidation product of a binuclear mixed-valence vanadium(IV,V) 8-quinolinol complex
✍ Hepler, Michelle A. (author);Riechel, Thomas L. (author) πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 293 KB

We have reported previously [l] on the chemical and electrochemical syntheses of a binuclear mixedvalence vanadium(IV,V) complex, [(V'"OQz)-O-(V"-0Q2)]-(Q-= 8-quinolinol anion). This complex undergoes a reversible one electron per dimer oxidation in acetonitrile. The oxidation product is stable and