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Identification of the oxidation product of a binuclear mixed-valence vanadium(IV,V) 8-quinolinol complex

✍ Scribed by Hepler, Michelle A. (author);Riechel, Thomas L. (author)


Book ID
104138109
Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
293 KB
Volume
54
Category
Article
ISSN
0020-1693

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Identification of the oxidation product
✍ Hepler, Michelle A. (author);Riechel, Thomas L. (author) πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 English βš– 293 KB

We have reported previously [l] on the chemical and electrochemical syntheses of a binuclear mixedvalence vanadium(IV,V) complex, [(V'"OQz)-O-(V"-0Q2)]-(Q-= 8-quinolinol anion). This complex undergoes a reversible one electron per dimer oxidation in acetonitrile. The oxidation product is stable and