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Triaquabis(4-formylbenzoato-κ2O,O′)cadmium(II) trihydrate

✍ Scribed by Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
277 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title complex, [Cd(C~8~H~5~O~3~)~2~(H~2~O)~3~]·3H~2~O, is a neutral mononuclear molecule consisting of a Cd^II^ atom chelated by two 4-formylbenzoate ligands and coordinated by three water molecules in a pentagonal–bipyramidal geometry. A three-dimensional hydrogen-bonded supramolecular network is formed by intermolecular hydrogen bonds.

📜 SIMILAR VOLUMES

Bis(4-formyl­benzoato-κ2O,O′)(1,10-phena
Bis(4-formyl­benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium(II)–bis­(μ2-4-formyl­benzoato-κ2O:O′)­bis­[(4-formyl­benzoato-κ2O,O′)(1,10-phenanthroline-κ2N,N′)cadmium(II)] (1/1)
✍ Deng, Zhao-Peng ;Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 307 KB

Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1

Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,1
Aquabis(4-formylbenzoato)-κ2O,O′;κO-(1,10-phenanthroline-κ2N,N′)cadmium(II)
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 683 KB

The Cd^II^ atom in the title complex, [Cd(C~8~H~5~O~3~)~2~(C~12~H~8~N~2~)(H~2~O)], is coordinated by three O atoms of two formylbenzoate ligands, two N atoms of a 1,10-phenanthroline ligand and one water molecule, giving rise to a trigonal–prismatic coordination geometry. Adjacent complex molecules

Aqua(2,2′-bipyridine-κ2N,N′)bis(4-formyl
Aqua(2,2′-bipyridine-κ2N,N′)bis(4-formylbenzoato-κ2O,O′)cadmium(II) monohydrate
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 807 KB

In the mononuclear title compound, [Cd(C~8~H~5~O~3~)~2~(C~10~H~8~N~2~)(H~2~O)]·H~2~O, the Cd atom is __O__,__O__′-chelated by two 4-formylbenzoate monoanions and __N__,__N__′-chelated by 2,2′-bipyridine. It is also coordinated by a water molecule in a monocapped trigonal-prismatic geometry. The coor