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Triaqua[(4-nitrophenylsulfonyl)acetato-κO](1,10-phenanthroline-κ2N,N′)cobalt(II) (4-nitrophenylsulfonyl)acetate monohydrate

✍ Scribed by Hou, Yan-Jun ;Yu, Ying-Hui ;Sun, Zhi-Zhong ;Li, Bai-Yan ;Hou, Guang-Feng

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
668 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Co(C 8 H 6 NO 6 S)(C 12 H 8 N 2 )(H 2 O) 3 ]-(C 8 H 6 NO 6 S)ÁH 2 O, the Co II atom shows an octahedral coordination, the geometry being defined by a carboxylate O atom from a 4-nitrophenylsulfonylacetate anion, two N atoms from the phenanthroline ligand and three water molecules. The molecules of the complex are linked by O-HÁ Á ÁO hydrogen bonds, which also involve the solvent water molecule, to form a linear chain structure.

Related literature

For related literature on metal arylsulfonylacetates, see: Gao et al. (2006); Hou et al. (2007); Shi et al. (2007). For related literature on the synthesis of 4-nitrophenylsulfonylacetic acid, see: Nobles & Thompson (1965).

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